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DOI : 10.17640/KSWST.2018.26.2.53 ,    Vol.26, No.2, 53 ~ 65, 2018
Title
Use of Hybrid Bead, Tannin and Chitosan, for Treatment of Pb(II) from Aqueous Solution
유성환 Sungwhan Yu , 최희정 Hee-jeong Choi
Abstract
In this study, hybrid beads were prepared using tannin and chitosan. Batch experiments were carried out to remove Pb(II) from aqueous solution using hybrid bead. According to the FT-IR analysis, the hybrid beads had carboxylic, carbonyl groups, carboxylic acids, and bonded-OH groups, which made it very easy to adsorb heavy metals. The adsorption of Pb(II) using hybrid beads was suitable for pseudo-second-order and Langmuir isotherms. The maximum adsorption capacity of Langmuir was 123.19 mg/g of Pb(II). The adsorption strength of Pb(II) to the hybrid bead was high and showed the isothermal adsorption characteristics of L type. In the thermodynamic experiment, ΔG° shows a negative value, and ΔH° and ΔS° show a positive value. It can be seen that the adsorption process of Pb(II) using hybrid bead is a spontaneous endothermic reaction and the affinity between adsorbent and adsorbate is very good. Hybrid beads can efficiently adsorb and remove Pb(II) as an inexpensive and environmentally friendly adsorbent.
Key Words
Adsorption, Chitosan, Hybrid bead, Lead, Persimmon leaf, Tannin
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