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DOI : 10.17640/KSWST.2015.23.2.81 ,    Vol.23, No.2, 81 ~ 91, 2015
Title
Competitive Adsorption of The Pollutants and Changes of The THM Formation Potentials in BAC Process
한명호 Myung Ho Han
Abstract
This study was undertaken to treat the aqueous solutions containing the organic pollutants, PCP(p-chlorophenol) and DBS(sodium dodecyl benzene sulfonate), by adsorption and biofilm processes using activated carbon fiber(ACF A-15) packed columns. And the changes of trihalomethane formation potentials(THMFP) in the model experimental system was investigated to clarify the mechanisms of the decrease/increase of THMFP in the biological activated carbon treatment. When adsorption of bi-components solution(PCP and DBS) was progressed, DBS , which was initially adsorbed, was replaced by PCP. The final adsorption capacities for these components at SV(space velocity) of 3.6h-1 were in good agreement with the batch single adsorption measurement, but for the SV of 11.3h-1, the adsorption capacity for DBS was found to be decreased. The removal efficiencies for DBS and PCP in bi-components system, were over 50% and 70%, respectively by BAC treatment. In case of treating the bi-components solution(PCP and DBS) mixed with raw stream water, the removal efficiencies for these components were greatly improved to over 90%. It was found that DBS restrains the THMFPs of PCP more or less. However, from the THMFP removal point of view, treating the bi-components (PCP and DBS) feed solution mixed with raw stream water containing abundant biomass, appeared to be more effective than treating the bi-components solution without raw stream water.
Key Words
PCP, p-chlorophenol, DBS, sodium dodecyl benzene sulfonate, THMFP, Trihalomethane Formation Potential, BAC, Biological Activated Carbon, ACF, Activated Carbon Fiber
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